((R,R)-2-amino-1,2-diphenylethyl)[(4-tolyl)sulfonyl]amido](p-cymene)ruthenium(ii)chloride
((R,R)-2-amino-1,2-diphenylethyl)[(4-tolyl)sulfonyl]amido](p-cymene)ruthenium(ii)chloride
CAS: 192139-92-7
Molecular Formula: C21H21ClN2O2RuS.C10H14
((R,R)-2-amino-1,2-diphenylethyl)[(4-tolyl)sulfonyl]amido](p-cymene)ruthenium(ii)chloride - Names and Identifiers
| Name | ((R,R)-2-amino-1,2-diphenylethyl)[(4-tolyl)sulfonyl]amido](p-cymene)ruthenium(ii)chloride |
| Synonyms | RuCl(p-cymene)[(R,R)-Ts-DPEN] (1R,2R)-2-amino-1,2-diphenylethyl]-(4-methylphenyl)sulfonylazanide ((R,R)-2-AMINO-1,2-DIPHENYLETHYL)[(4-TOLYL)SULFONYL]AMIDO](P-CYMENE)RUTHENIUM(II)CHLORIDE ((R,R)-2-amino-1,2-diphenylethyl)[(4-tolyl)sulfonyl]amido](p-cymene)ruthenium(ii)chloride Chloro{[(1R,2R)-(-)-2-amino-1,2-diphenylethyl](4-toluenesulfonyl)amido}(p-cymene)ruthenium(II) |
| CAS | 192139-92-7 |
| InChI | InChI=1/C21H21N2O2S.C10H14.ClH.Ru/c1-16-12-14-19(15-13-16)26(24,25)23-21(18-10-6-3-7-11-18)20(22)17-8-4-2-5-9-17;1-8(2)10-6-4-9(3)5-7-10;;/h2-15,20-21H,22H2,1H3;4-8H,1-3H3;1H;/q-1;;;+2/p-1/t20-,21-;;;/m1.../s1/rC21H21ClN2O2RuS.C10H14/c1-16-12-14-19(15-13-16)28(25,26)24(27-22)21(18-10-6-3-7-11-18)20(23)17-8-4-2-5-9-17;1-8(2)10-6-4-9(3)5-7-10/h2-15,20-21H,23H2,1H3;4-8H,1-3H3/t20-,21-;/m1./s1 |
((R,R)-2-amino-1,2-diphenylethyl)[(4-tolyl)sulfonyl]amido](p-cymene)ruthenium(ii)chloride - Physico-chemical Properties
| Molecular Formula | C21H21ClN2O2RuS.C10H14 |
| Molar Mass | 636.219 |
| Melting Point | 215°C |
| Solubility | Deuterated Chloroform, DMF |
| Appearance | solid |
| Color | yellow to dark brown |
| Storage Condition | 2-8°C |
| Sensitive | air sensitive |
((R,R)-2-amino-1,2-diphenylethyl)[(4-tolyl)sulfonyl]amido](p-cymene)ruthenium(ii)chloride - Risk and Safety
| WGK Germany | 3 |
| HS Code | 28439000 |
((R,R)-2-amino-1,2-diphenylethyl)[(4-tolyl)sulfonyl]amido](p-cymene)ruthenium(ii)chloride - Introduction
Chloro {[(1R,2R)-(-)-2-amino-1, 2-diphenylethyl] (4-toluenesulfonyl) ammonia}(P-isopropyltoluene) ruthenium (II), abbreviated as Cymene ruthenium (II), is an organic complex containing ruthenium. The following is a description of some properties, uses, preparation methods and safety information of the compound:
Nature:
-Appearance: Cymene ruthenium (II) is a white to light yellow solid.
-Solubility: It is soluble in common organic solvents such as dichloromethane, ether and methanol.
Use:
Cymene ruthenium (II) has important applications in homogeneous catalytic reactions. It can be used to catalyze various organic reactions, including hydrogenation, oxidation, olefin isotope exchange, etc. In addition, it can also be used for hydrogen transfer and selective oxidation reactions in organic synthesis.
Method:
The preparation of Cymene ruthenium (II) can be obtained by reacting the ammonia complex of ruthenium with ammonium chloride. Specific procedures typically involve the synthesis of a precursor complex of ruthenium, which is then generated by treatment with sodium chloride in an ammonia solution.
Safety Information:
-The specific hazards of Cymene ruthenium (II) are not yet clear. However, like other organometallic complexes, Good Laboratory Practice measures should be followed and used and stored under suitable conditions.
-Attention should be paid to the risk of skin contact and inhalation. Wear appropriate protective equipment such as lab gloves, goggles and chemical protective clothing during use.
-If you come into contact with this substance, rinse immediately with plenty of water and seek medical help.
Please note that Cymene ruthenium (II) is a specialized compound and should only be used under appropriate laboratory conditions and in accordance with relevant laboratory safety procedures.
Nature:
-Appearance: Cymene ruthenium (II) is a white to light yellow solid.
-Solubility: It is soluble in common organic solvents such as dichloromethane, ether and methanol.
Use:
Cymene ruthenium (II) has important applications in homogeneous catalytic reactions. It can be used to catalyze various organic reactions, including hydrogenation, oxidation, olefin isotope exchange, etc. In addition, it can also be used for hydrogen transfer and selective oxidation reactions in organic synthesis.
Method:
The preparation of Cymene ruthenium (II) can be obtained by reacting the ammonia complex of ruthenium with ammonium chloride. Specific procedures typically involve the synthesis of a precursor complex of ruthenium, which is then generated by treatment with sodium chloride in an ammonia solution.
Safety Information:
-The specific hazards of Cymene ruthenium (II) are not yet clear. However, like other organometallic complexes, Good Laboratory Practice measures should be followed and used and stored under suitable conditions.
-Attention should be paid to the risk of skin contact and inhalation. Wear appropriate protective equipment such as lab gloves, goggles and chemical protective clothing during use.
-If you come into contact with this substance, rinse immediately with plenty of water and seek medical help.
Please note that Cymene ruthenium (II) is a specialized compound and should only be used under appropriate laboratory conditions and in accordance with relevant laboratory safety procedures.
Last Update：2024-04-09 20:52:54
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View History
((R,R)-2-amino-1,2-diphenylethyl)[(4-tolyl)sulfonyl]amido](p-cymene)ruthenium(ii)chloride
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